Homochiral coordination polymeric gel: Zn(2+)-induced conformational changes leading to J-aggregated helical fibres formation.
نویسندگان
چکیده
A novel chiral coordination polymeric gel based on an amino acid derived symmetrical ligand, specific base, and Zn(2+) has been described. Zn(2+) induced conformational reorganization in the ligand leads to gelation via J-aggregated helical fibres. The vital role played by π-π stacking in gelation has been monitored by fluorescence and NMR spectroscopy.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 14 شماره
صفحات -
تاریخ انتشار 2014